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Evolution of poling-assisted bleaching of metal-doped nanocomposite glass with poling conditions

Evolution of poling-assisted bleaching of metal-doped nanocomposite glass with poling conditions

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Authors

  • Olivier Deparis
  • Peter G. Kazansky
  • Alexander Podlipensky
  • Amin Abdolvand
  • Gerhard Seifert
  • Heinrich Graener

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Info

Original languageEnglish
Article number261109
Number of pages3
JournalApplied Physics Letters
Journal publication date2005
Volume86
Issue26
DOIs
StatePublished

Abstract

Poling-assisted bleaching was studied with respect to poling time, voltage, and temperature in glass samples having a gradient of silver nanoparticles across the depth. The optical extinction band due to the particles' surface plasmon resonance (around 415 nm) was measured and the Maxwell-Garnett effective medium theory was used to fit extinction spectra. Fitting allowed us to determine the evolution of the thickness of the near-surface layer where the particles' volume filling factor has dropped to zero as a result of the bleaching process. At 280 degrees C, bleaching started with a voltage as low as 200 V and saturated with time after about 1 h. Tight glass-electrode contact, voltage of at least 1 kV, and temperature higher than 200 degrees C were required in order to obtain significant and uniform bleaching in the poled area. The results were discussed in terms of the underlying electric-field-assisted dissolution of embedded metal nanoparticles.

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