Borate retardation of cement set and phase relations in the system Na2O-CaO-B2O3-H2O

L. J. Csetenyi; F. P. Glasser

doi:10.1680/adcr.1995.7.25.13

Borate retardation of cement set and phase relations in the system Na₂O-CaO-B₂O₃-H₂O

L. J. Csetenyi, F. P. Glasser

Civil Engineering

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

The CaO-rich portions of this system have been determined at 25° and 55 °C. Twenty-one closely spaced compositions were prepared from analytical reagent-grade materials and reacted in sealed containers for up to 6 months. Solid phases were characterized mainly by X-ray diffraction and the aqueous phase was analysed chemically for Ca, Na and B. Solubility data were also obtained from single-phase preparations of selected hydrates; in conjunction with data in the literature, extensive thermodynamic modelling of solubility relations was undertaken. The combination of calculation and experimental determinations enabled the equilibrium features to be determined rapidly; cross-checks between calculated and experimental data are presented.

Original language	English
Pages (from-to)	13-19
Number of pages	7
Journal	Advances in Cement Research
Volume	7
Issue number	25
DOIs	https://doi.org/10.1680/adcr.1995.7.25.13
Publication status	Published - 1 Jan 1995

ASJC Scopus subject areas

Building and Construction
General Materials Science

Access to Document

10.1680/adcr.1995.7.25.13

Cite this

@article{0c773364e5314f94890c6751d5ccab8c,

title = "Borate retardation of cement set and phase relations in the system Na2O-CaO-B2O3-H2O",

abstract = "The CaO-rich portions of this system have been determined at 25° and 55 °C. Twenty-one closely spaced compositions were prepared from analytical reagent-grade materials and reacted in sealed containers for up to 6 months. Solid phases were characterized mainly by X-ray diffraction and the aqueous phase was analysed chemically for Ca, Na and B. Solubility data were also obtained from single-phase preparations of selected hydrates; in conjunction with data in the literature, extensive thermodynamic modelling of solubility relations was undertaken. The combination of calculation and experimental determinations enabled the equilibrium features to be determined rapidly; cross-checks between calculated and experimental data are presented.",

author = "Csetenyi, {L. J.} and Glasser, {F. P.}",

year = "1995",

month = jan,

day = "1",

doi = "10.1680/adcr.1995.7.25.13",

language = "English",

volume = "7",

pages = "13--19",

journal = "Advances in Cement Research",

issn = "0951-7197",

publisher = "Thomas Telford",

number = "25",

}

TY - JOUR

T1 - Borate retardation of cement set and phase relations in the system Na2O-CaO-B2O3-H2O

AU - Csetenyi, L. J.

AU - Glasser, F. P.

PY - 1995/1/1

Y1 - 1995/1/1

N2 - The CaO-rich portions of this system have been determined at 25° and 55 °C. Twenty-one closely spaced compositions were prepared from analytical reagent-grade materials and reacted in sealed containers for up to 6 months. Solid phases were characterized mainly by X-ray diffraction and the aqueous phase was analysed chemically for Ca, Na and B. Solubility data were also obtained from single-phase preparations of selected hydrates; in conjunction with data in the literature, extensive thermodynamic modelling of solubility relations was undertaken. The combination of calculation and experimental determinations enabled the equilibrium features to be determined rapidly; cross-checks between calculated and experimental data are presented.

AB - The CaO-rich portions of this system have been determined at 25° and 55 °C. Twenty-one closely spaced compositions were prepared from analytical reagent-grade materials and reacted in sealed containers for up to 6 months. Solid phases were characterized mainly by X-ray diffraction and the aqueous phase was analysed chemically for Ca, Na and B. Solubility data were also obtained from single-phase preparations of selected hydrates; in conjunction with data in the literature, extensive thermodynamic modelling of solubility relations was undertaken. The combination of calculation and experimental determinations enabled the equilibrium features to be determined rapidly; cross-checks between calculated and experimental data are presented.

UR - http://www.scopus.com/inward/record.url?scp=0029219322&partnerID=8YFLogxK

U2 - 10.1680/adcr.1995.7.25.13

DO - 10.1680/adcr.1995.7.25.13

M3 - Article

AN - SCOPUS:0029219322

SN - 0951-7197

VL - 7

SP - 13

EP - 19

JO - Advances in Cement Research

JF - Advances in Cement Research

IS - 25

ER -

Borate retardation of cement set and phase relations in the system Na₂O-CaO-B₂O₃-H₂O

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this