Deep removal of arsenic from regenerated products of spent V2O5-WO3/TiO2 SCR catalysts and its concurrent activation by bioleaching through a novel mechanism

Tianqi Niu, Jia Wang, Huichao Chu, Can Qian, Ning Duan, Geoffrey Michael Gadd, Wen Shi, Baoping Xin (Lead / Corresponding author)

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    29 Citations (Scopus)
    165 Downloads (Pure)

    Abstract

    Selective catalytic reaction (SCR) is widely used in flue gas denitrification to convert NOx air pollutants into N2 and H2O in the presence of SCR catalyst, but arsenic poisoning causes serious deactivation of SCR catalyst and produces a huge amount of spent SCR catalyst worldwide. Therefore, the regeneration and recycling of spent SCR catalysts are of great necessity for the sustainable flue gas denitrification due to the very high cost of replacing commercial catalysts. Nowadays, a combination of alkali treatment and acid washing is usually used to regenerate spent SCR catalysts. However, high residue of As strongly inhibits the catalytic activity of the regenerated products. In this study, an active bioleaching liquor produced by Acidithiobacillus thiooxidans as indirect bioleaching was attempted to deeply remove As from the regenerated product for the first time. The results showed that bioleaching resulted in maximal As removal of 53.1% even at a high pulp density of 10% to harvest a minimum As residue of 174 mg/kg below the limiting value of 200 mg/kg; whereas H2SO4 leaching attained 6.7% As removal and as high as 345 mg/kg of As residue. A stronger activation of the regenerated products simultaneously occurred with the bioleaching. A great amount of cysteine in the bioleaching liquor secreted by the microbe accounts for both the enhancement of As removal and strong activation of the product. A novel mechanism is proposed to explain the excellent As removal by the indirect bioleaching based on nucleophilic attack of the sulfhydryl groups in cysteine.

    Original languageEnglish
    Article number127722
    Number of pages15
    JournalChemical Engineering Journal
    Volume420
    Early online date16 Nov 2020
    DOIs
    Publication statusPublished - 15 Sept 2021

    Keywords

    • Arsenic removal
    • Bioleaching
    • Endogenous cysteine
    • Regenerated product
    • Spent catalyst

    ASJC Scopus subject areas

    • General Chemistry
    • Environmental Chemistry
    • General Chemical Engineering
    • Industrial and Manufacturing Engineering

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