Hyper-Raman selection rules for molecules possessing cubic symmetry

Trevor J. Dines

doi:10.1016/j.cplett.2008.05.004

Hyper-Raman selection rules for molecules possessing cubic symmetry

Trevor J. Dines

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Non-symmetric components of the transition hyperpolarizability are shown to be zero for molecules possessing cubic symmetry. Consequently, the vibrational hyper-Raman selection rules for such species are governed solely by a fully symmetric hyperpolarizability tensor and it is predicted that vibrational hyper-Raman scattering from octahedral molecules is very weak. (c) 2008 Elsevier B. V. All rights reserved.

Original language	English
Pages (from-to)	180-182
Number of pages	3
Journal	Chemical Physics Letters
Volume	459
Issue number	1-6
DOIs	https://doi.org/10.1016/j.cplett.2008.05.004
Publication status	Published - 27 Jun 2008

Keywords

LIGHT SCATTERING
SOFT-MODE
SPECTROSCOPY
POLARIZATION
SPECTRA

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10.1016/j.cplett.2008.05.004

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title = "Hyper-Raman selection rules for molecules possessing cubic symmetry",

abstract = "Non-symmetric components of the transition hyperpolarizability are shown to be zero for molecules possessing cubic symmetry. Consequently, the vibrational hyper-Raman selection rules for such species are governed solely by a fully symmetric hyperpolarizability tensor and it is predicted that vibrational hyper-Raman scattering from octahedral molecules is very weak. (c) 2008 Elsevier B. V. All rights reserved.",

keywords = "LIGHT SCATTERING, SOFT-MODE, SPECTROSCOPY, POLARIZATION, SPECTRA",

author = "Dines, \{Trevor J.\}",

year = "2008",

month = jun,

day = "27",

doi = "10.1016/j.cplett.2008.05.004",

language = "English",

volume = "459",

pages = "180--182",

journal = "Chemical Physics Letters",

issn = "0009-2614",

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T1 - Hyper-Raman selection rules for molecules possessing cubic symmetry

AU - Dines, Trevor J.

PY - 2008/6/27

Y1 - 2008/6/27

N2 - Non-symmetric components of the transition hyperpolarizability are shown to be zero for molecules possessing cubic symmetry. Consequently, the vibrational hyper-Raman selection rules for such species are governed solely by a fully symmetric hyperpolarizability tensor and it is predicted that vibrational hyper-Raman scattering from octahedral molecules is very weak. (c) 2008 Elsevier B. V. All rights reserved.

AB - Non-symmetric components of the transition hyperpolarizability are shown to be zero for molecules possessing cubic symmetry. Consequently, the vibrational hyper-Raman selection rules for such species are governed solely by a fully symmetric hyperpolarizability tensor and it is predicted that vibrational hyper-Raman scattering from octahedral molecules is very weak. (c) 2008 Elsevier B. V. All rights reserved.

KW - LIGHT SCATTERING

KW - SOFT-MODE

KW - SPECTROSCOPY

KW - POLARIZATION

KW - SPECTRA

U2 - 10.1016/j.cplett.2008.05.004

DO - 10.1016/j.cplett.2008.05.004

M3 - Article

SN - 0009-2614

VL - 459

SP - 180

EP - 182

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-6

ER -

Hyper-Raman selection rules for molecules possessing cubic symmetry

Abstract

Keywords

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