Modelling performance of two- and four-terminal thin-film silicon tandem solar cells under varying spectral conditions

Stephen Reynolds (Lead / Corresponding author), Vladimir Smirnov

    Research output: Contribution to journalArticlepeer-review

    9 Citations (Scopus)
    190 Downloads (Pure)

    Abstract

    In an amorphous silicon/microcrystalline silicon or ‘micromorph’ tandem solar cell, variations in solar spectral quality alter the proportion of photo-generated current developed by each sub-cell. This imbalance may reduce long-term energy conversion efficiency, compared with operation under a constant AM1.5G spectrum. Using semi-empirical modelling, we contrast the usual series-connected two-terminal tandem cell, constrained by current-matching, with a four-terminal tandem cell, in which both sub-cells are electrically independent. The model reveals that reduction in extracted power due to current mismatch in two-terminal connection is compensated somewhat by an increase in fill-factor either side of the current-matched point. The efficiency-mismatch curve is compared with spectral distributions of annual insolation in terms of average photon energy. Provided the two-terminal cell is matched to the prevailing spectral distribution, long-term benefits in electrical energy output in four-terminal connection are predicted to be modest. However departures from the AM1.5G spectrum occur worldwide, and this plus the flexibility to match to seasonal degradation/annealing cycles suggests that four-terminal connection may offer greater benefit.
    Original languageEnglish
    Pages (from-to)251-260
    Number of pages10
    JournalEnergy Procedia
    Volume84
    Early online date29 Dec 2015
    DOIs
    Publication statusPublished - Dec 2015
    EventEMRS 2015 Spring Meeting: Symposium C - Advanced Inorganic Materials and Structures for Photovoltaics - Lille Grand Palais, Lille, France
    Duration: 11 May 201515 May 2015
    http://www.european-mrs.com/2015-spring-symposium-c-european-materials-research-society

    Keywords

    • Tandem solar cells
    • Computer modelling
    • Solar spectrum
    • Current matching

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