Photoswitchable molecular dipole antennas with tailored coherent coupling in glassy composite

Mady Elbahri (Lead / Corresponding author), Ahnaf Usman Zillohu, Bastian Gothe, Mehdi Keshavarz Hedayati, Ramzy Abdelaziz, Hala Jarallah El-Khozondar, Muhammad Bawa'Aneh, Moheb Abdelaziz, Andrei Lavrinenko, Sergei Zhukovsky, Shahin Homaeigohar

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)
11 Downloads (Pure)

Abstract

Here, we introduce the first experimental proof of coherent oscillation and coupling of photoswitchable molecules embedded randomly in a polymeric matrix and acting cooperatively upon illumination with UV light. In particular, we demonstrate the specular reflection and Brewster phenomenon alteration of photochromic molecular dipole antennas. We successfully demonstrate the concept of Brewster wavelength, which is based on the dipolar interaction between radiating dipoles and the surrounding matrix possessing a net dipole moment, as a key tool for highly localized sensing of matrix polarity. We also introduce the concept of 'tailored molecular photonic coupling' while highlighting the role of interferences for the design of optically active media by adjusting the photonic response of the medium with the real and imaginary refractive index of photoswitchable molecules in the 'ON' state. Our results enhance our fundamental understanding of coherent dipole radiation and open a new vein of research based on glassy disordered dipolar composites that act as macroscopic antenna with cooperative action; furthermore, these results have important implications for new design rules of tailored photonics.

Original languageEnglish
Article numbere316
Number of pages8
JournalLight: Science and Applications
Volume4
Issue number7
Early online date31 Jul 2015
DOIs
Publication statusPublished - Jul 2015

Keywords

  • Brewster angle
  • Coherent coupling
  • Collective oscillation
  • Photoswitchable molecular photonics
  • Specular reflection

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