Rapid, quantitative, and site specific synthesis of biomolecular radicals from a simple photocaged precursor

Tony Ly; Xing Zhang; Qingyu Sun; Benjamin Moore; Yuanqi Tao; Ryan R. Julian

doi:10.1039/c0cc03363d

Rapid, quantitative, and site specific synthesis of biomolecular radicals from a simple photocaged precursor

Tony Ly, Xing Zhang, Qingyu Sun, Benjamin Moore, Yuanqi Tao, Ryan R. Julian (Lead / Corresponding author)

Plant Sciences

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

Novel p-iodobenzoate-based labelling reagents are shown to be effective photocaged precursors for synthesizing biomolecular radicals site-selectively in the gaseous and condensed phases. In vacuo, a single pulse of UV photons (266 nm) is sufficient to quantitatively photolyse the C–I bond. In aqueous solutions, the photolysis half-life is estimated to be 2.5 minutes when irradiating with a 15 W compact fluorescent lamp (254 nm).

Original language	English
Pages (from-to)	2835-2837
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	10
Early online date	24 Jan 2011
DOIs	https://doi.org/10.1039/c0cc03363d
Publication status	Published - 14 Mar 2011

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title = "Rapid, quantitative, and site specific synthesis of biomolecular radicals from a simple photocaged precursor",

abstract = "Novel p-iodobenzoate-based labelling reagents are shown to be effective photocaged precursors for synthesizing biomolecular radicals site-selectively in the gaseous and condensed phases. In vacuo, a single pulse of UV photons (266 nm) is sufficient to quantitatively photolyse the C–I bond. In aqueous solutions, the photolysis half-life is estimated to be 2.5 minutes when irradiating with a 15 W compact fluorescent lamp (254 nm).",

author = "Tony Ly and Xing Zhang and Qingyu Sun and Benjamin Moore and Yuanqi Tao and Julian, {Ryan R.}",

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AU - Ly, Tony

AU - Zhang, Xing

AU - Sun, Qingyu

AU - Moore, Benjamin

AU - Tao, Yuanqi

AU - Julian, Ryan R.

PY - 2011/3/14

Y1 - 2011/3/14

N2 - Novel p-iodobenzoate-based labelling reagents are shown to be effective photocaged precursors for synthesizing biomolecular radicals site-selectively in the gaseous and condensed phases. In vacuo, a single pulse of UV photons (266 nm) is sufficient to quantitatively photolyse the C–I bond. In aqueous solutions, the photolysis half-life is estimated to be 2.5 minutes when irradiating with a 15 W compact fluorescent lamp (254 nm).

AB - Novel p-iodobenzoate-based labelling reagents are shown to be effective photocaged precursors for synthesizing biomolecular radicals site-selectively in the gaseous and condensed phases. In vacuo, a single pulse of UV photons (266 nm) is sufficient to quantitatively photolyse the C–I bond. In aqueous solutions, the photolysis half-life is estimated to be 2.5 minutes when irradiating with a 15 W compact fluorescent lamp (254 nm).

U2 - 10.1039/c0cc03363d

DO - 10.1039/c0cc03363d

M3 - Article

SN - 1359-7345

VL - 47

SP - 2835

EP - 2837

JO - Chemical Communications

JF - Chemical Communications

IS - 10

ER -

Rapid, quantitative, and site specific synthesis of biomolecular radicals from a simple photocaged precursor

Abstract

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