Selective Electroless Copper Deposition by Using Photolithographic Polymer/Ag Nanocomposite

Assel Ryspayeva, Thomas D. A. Jones, Mohammadreza Nekouie Esfahani, Matthew P. Shuttleworth, Russell A. Harris, Robert W. Kay, Marc P. Y. Desmulliez, Jose Marques-hueso

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Abstract

This paper presents a novel, direct, selective, vacuum-free, and low-cost method of electroless copper deposition, allowing additive patterning of nonconductive surfaces. Ag nanoparticles (NPs) synthesized inside a photosensitive polymer are acting as seeds for electroless copper deposition. The resulting copper film surface morphology was studied with scanning electron microscopy. Copper films were shown to display a rough grainlike structure, covering substrate uniformly with good metal-substrate adhesion. Copper thickness was studied as a function of the plating time, temperature, and Ag NPs seed concentration. A maximal copper thickness of 0.44 ± 0.05 μm was achieved when plated at 30 °C with 0.4 M Ag(I). The minimum feature resolution of copper patterns, grown with 0.025- and 0.1-M silver salt, is attained down to 10 μm. The maximum electrical conductivity of the copper film prepared with 0.025-, 0.1-, and 0.4-M Ag(I) approaches (0.8 ± 0.1) × 107 S/m, (1.1 ± 0.1)×107 S/m and (1.6 ± 0.4)×107 S/m, respectively. Electroless copper interconnections and LED circuit on glass substrate were fabricated as a proof of concept demonstrators.
Original languageEnglish
Article number8643047
Pages (from-to)1843-1848
Number of pages6
JournalIEEE Transactions on Electron Devices
Volume66
Issue number4
DOIs
Publication statusPublished - Apr 2019

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Keywords

  • Ag nanoparticles (NPs) seeds
  • electroless copper
  • metallization of nonconductive surfaces
  • polymer/Ag nanocomposite

Cite this

Ryspayeva, A., Jones, T. D. A., Esfahani, M. N., Shuttleworth, M. P., Harris, R. A., Kay, R. W., Desmulliez, M. P. Y., & Marques-hueso, J. (2019). Selective Electroless Copper Deposition by Using Photolithographic Polymer/Ag Nanocomposite. IEEE Transactions on Electron Devices, 66(4), 1843-1848. [8643047]. https://doi.org/10.1109/TED.2019.2897258