Structural and optical properties of alloyed quaternary CdSeTeS core and CdSeTeS/ZnS core-shell quantum dots

Oluwasesan Adegoke, Tebello Nyokong, Patricia B. C. Forbes (Lead / Corresponding author)

Research output: Contribution to journalArticlepeer-review

38 Citations (Scopus)


Synthesis of fluorescent alloyed quantum dots (QDs) with unique optical properties suitable for a wide array of chemical, physical and biological applications is of research interest. In this work, highly luminescent and photostable alloyed quaternary CdSeTeS core QDs of two different sizes were fabricated via the organometallic hot-injection synthetic route. Characterization of the nanocrystals were performed using TEM, XRD, UV/vis and fluorescence spectrophotometric techniques. We have demonstrated in this work that the well fabricated alloyed quaternary CdSeTeS core QDs possess unique optical properties that are advantageous over conventional core/shell systems. Formation of the CdSeTeS/ZnS core/shell with the desired optical properties comes with a number of challenges, hence the advantages of the quaternary alloyed core over the core/shell QDs are (i) avoidance of the challenging process of determining the proper shell thickness which can provide the desired optical properties in the core/shell system and (ii) avoidance of the lattice-induced mismatch between the core and the shell material which can either lead to incomplete exciton confinement or dislocation at the core/shell interface.
Original languageEnglish
Pages (from-to)443-449
Number of pages7
JournalJournal of Alloys and Compounds
Early online date22 May 2015
Publication statusPublished - 5 Oct 2015


  • Quantum dots
  • Core/shell
  • Photoluminescence
  • Quantum yield
  • Alloy


Dive into the research topics of 'Structural and optical properties of alloyed quaternary CdSeTeS core and CdSeTeS/ZnS core-shell quantum dots'. Together they form a unique fingerprint.

Cite this