TY - JOUR
T1 - The improvement of electron transport rate of TiO2 dye-sensitized solar cells using mixed nanostructures with different phase compositions
AU - Bakhshayesh, A. M.
AU - Mohammadi, M. R.
N1 - Funding - Iran Nanotechnology Initiative Council
PY - 2013/9/1
Y1 - 2013/9/1
N2 - Dye-sensitized solar cells (DSCCs) in the form of mixed nanostructures containing TiO2 nanoparticles and nanowires with different weight ratios and phase compositions are reported. X-ray diffraction and field emission scanning electron microscopy analyses revealed that the synthesized TiO 2 nanoparticles had average crystallite size in the range 21-39 nm, whereas TiO2 nanowires showed diameter in the range 20-50 nm. The indirect optical band gap energy of TiO2 nanowires, anatase- and rutile-TiO2 nanoparticles was calculated to be 3.35, 3.28 and 3.17 eV, respectively. The power conversion efficiency of the solar cells changed with nanowire to nanoparticle weight ratio, reaching a maximum at a specific value. An increase of 4.3% in cell efficiency was achieved by introducing 10 wt% nanowire into the as-synthesized TiO2 nanoparticles (WP1 cell). Furthermore, an increase of 27.6% in cell efficiency was achieved by using crystalline anatase-TiO2 nanoparticles rather than as-synthesized TiO2 nanoparticles in WP1 solar cell. It was found that the power conversion efficiency and short circuit current of WP1 cell were decreased down to around 30.8% and 39.1%, respectively using rutile nanoparticles rather than anatase nanoparticles. The improvement of cell efficiency was related to rapid electron transport and less recombination of photogenerated electrons, as confirmed by electrochemical impedance spectroscopy.
AB - Dye-sensitized solar cells (DSCCs) in the form of mixed nanostructures containing TiO2 nanoparticles and nanowires with different weight ratios and phase compositions are reported. X-ray diffraction and field emission scanning electron microscopy analyses revealed that the synthesized TiO 2 nanoparticles had average crystallite size in the range 21-39 nm, whereas TiO2 nanowires showed diameter in the range 20-50 nm. The indirect optical band gap energy of TiO2 nanowires, anatase- and rutile-TiO2 nanoparticles was calculated to be 3.35, 3.28 and 3.17 eV, respectively. The power conversion efficiency of the solar cells changed with nanowire to nanoparticle weight ratio, reaching a maximum at a specific value. An increase of 4.3% in cell efficiency was achieved by introducing 10 wt% nanowire into the as-synthesized TiO2 nanoparticles (WP1 cell). Furthermore, an increase of 27.6% in cell efficiency was achieved by using crystalline anatase-TiO2 nanoparticles rather than as-synthesized TiO2 nanoparticles in WP1 solar cell. It was found that the power conversion efficiency and short circuit current of WP1 cell were decreased down to around 30.8% and 39.1%, respectively using rutile nanoparticles rather than anatase nanoparticles. The improvement of cell efficiency was related to rapid electron transport and less recombination of photogenerated electrons, as confirmed by electrochemical impedance spectroscopy.
KW - A. Sol-gel processes
KW - C. Electrical properties
KW - D. TiO
KW - Dye-sensitized solar cell
UR - http://www.scopus.com/inward/record.url?scp=84880265530&partnerID=8YFLogxK
U2 - 10.1016/j.ceramint.2013.02.073
DO - 10.1016/j.ceramint.2013.02.073
M3 - Article
AN - SCOPUS:84880265530
VL - 39
SP - 7343
EP - 7353
JO - Ceramics International
JF - Ceramics International
SN - 0272-8842
IS - 7
ER -